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Creators/Authors contains: "Gunasekera, Parami S."

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  1. ; ; ; ; ; ( , Journal of the American Chemical Society)
    Free, publicly-accessible full text available June 6, 2024
  2. ; ; ; ( , European Journal of Inorganic Chemistry)
    Abstract

    Neutral three‐coordinate iron alkylidenes of the form PN−Fe=CHR have been proposed as viable candidates for alkene metathesis. Indeed, during the final stages of preparing this current study, a separate report disclosed that dearomatized PN−Fe‐alkyl complexes are active precatalysts for ring‐opening metathesis polymerization (ROMP) of norbornene implicating PN−Fe=CHR species as possible intermediates. In yet another separate report, we prepared Zn analogues of PN−Fe‐alkyl complexes and herein provide an account for the synthesis, characterization, and reactivity of some new iron complexes with the sametBu substituted PN platform.

     
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  3. ; ; ; ; ( , Organometallics)
    Full Text Available